Inorganic and metallic nanotubular materials: recent technologies and applications / ed. by T.Kijima. - Berlin; Heidelberg: Springer, 2010. - xv, 295 p.: ill. - (Topics in applied physics; 117). - Incl. bibl. ref. - Ind.: p.287-295. - ISBN 978-3-642-03620-0  Место хранения:   058 | Институт физики прочности и материаловедения CO РАН | Томск | Библиотека

Оглавление / Contents

1 Introduction to Inorganic and Metallic Nanotubes Tsuyoshi Kijima .............................................. 1 1.1 Introduction ............................................ 1 1.2 Structural and Synthetic Bases for Inorganic and Metallic Nanotubes ...................................... 2 1.2.1 Structural Types of Nanotubes .................... 3 1.2.2 Synthetic Strategies Toward Nanotubes ............ 5 1.3 Structural and Dimensional Characteristics of Inorganic and Metallic Nanotubes ........................ 8 1.4 Applications of Inorganic and Metallic Nanotubes ....... 11 1.5 Concluding Remarks ..................................... 12 References .................................................. 13 Index ....................................................... 15 2 Synthesis and Applications of Titanium Oxide Nanotubes Tohru Sekino ................................................ 17 2.1 Introduction ........................................... 17 2.2 Synthesis and Structure of Titanium Oxide Nanotubes .... 19 2.2.1 Low Temperature Solution Chemical Processing .... 19 2.2.2 Nanostructures and Formation Mechanism .......... 21 2.3 Functions of Titanium Oxide Nanotubes .................. 25 2.3.1 Photochemical Properties and Photocatalytic Functions ....................................... 25 2.3.2 Novel Environmental Purification Functions ...... 27 2.3.3 Multi-functionalized Titanium Oxide Nanotubes ... 28 2.4 Conclusion and Prospects ............................... 30 References .................................................. 30 Index ....................................................... 32 3 Synthesis, Structural Analysis, and Applications of Titanium Oxide Nanotubes Tsuguo Koyanagi ............................................. 33 3.1 Introduction ........................................... 33 3.2 Synthesis of Mono-Dispersed Titanium Dioxide Nanotubes .............................................. 34 3.3 Nanostructure Analysis of Titanium Dioxide Nanotubes ... 35 3.4 Applications of Titanium Dioxide Nanotubes ............. 38 3.4.1 Application for Dye-Sensitized Solar Cells ...... 38 3.4.2 Application for Photo-Catalysis ................. 42 3.5 Summary ................................................ 43 References .................................................. 44 Index ....................................................... 44 4 Synthesis and Applications of Titanium Oxide Nanotube Thin Films Masahiro Miyauchi and Hiromasa Tokudome ..................... 45 4.1 Introduction ........................................... 45 4.2 Titanate Nanotube (TNT) Thin Films via Alternate Layer Deposition ....................................... 46 4.3 Thin Films of Vertically Aligned TNT Arrays and Their Applications ........................................... 51 4.4 Conclusions ............................................ 55 References .................................................. 55 Index ....................................................... 57 5 Synthesis and Application of Titanium Oxide Nanohole Arrays Shinsuke Yamanaka and Masayoshi Uno ......................... 59 5.1 Introduction ........................................... 59 5.2 Formation Mechanism and Properties ..................... 61 5.3 Application as an Electrode for Lithium Ion Batteries .............................................. 66 5.4 Nanohole Arrays of Various Oxides ...................... 68 5.5 Summary ................................................ 70 References .................................................. 70 Index ....................................................... 71 6 Synthesis and Applications of Manganese Oxide Nanotubes Qi Feng ..................................................... 73 6.1 Single-Crystal Manganese Oxide Nanotubes ............... 73 6.1.1 Crystal Structures of Layered Manganese Oxides .......................................... 73 6.1.2 Manganese Oxide Nanotubes Synthesized from Manganese Oxide Nanosheets ................. 74 6.1.3 Manganese Oxide Nanotubes Synthesized from α-NaMnO2 ........................................ 78 6.1.4 Manganese Oxide Nanotubes Synthesized Directly from Mn(Ac)2 Solution .................. 79 6.2 Polycrystalline Manganese Oxide Nanotubes .............. 80 6.3 Summary ................................................ 81 References .................................................. 81 Index ....................................................... 82 7 Synthesis and Applications of Molybdenum Oxide Nanotubes Maki Suemitsu and Toshimi Abe ............................... 83 7.1 Introduction ........................................... 83 7.2 Growth of Molybdenum Oxide Nanotubes ................... 84 7.3 The Chemical Composition and the Crystal Structure of the Mo Oxide Nanotubes .............................. 85 7.4 Growth Mechanism of the Mo Oxide Nanotubes ............. 89 7.5 Conclusion ............................................. 94 References .................................................. 95 Index ....................................................... 96 8 Synthesis and Applications of Rare-Earth Compound Nanotubes Mitsunori Yada .............................................. 97 8.1 Introduction ........................................... 97 8.2 Rare-Earth Compound Nanotubes Synthesized Using the Homogeneous Precipitation Method ................... 98 8.3 Rare-Earth Hydroxide and Rare-Earth Oxide Nanotubes Synthesized Using the Hydrothermal Method ............. 102 8.4 Rare-Earth Oxide Nanotubes Synthesized Using Carbon Nanotube as a Template ................................ 107 8.5 Rare-Earth Oxide Nanotubes Synthesized Using Anodic Alumina Membrane as a Template ........................ 108 8.6 Cerium Phosphate Nanotubes with Blue Luminescence ..... 108 8.7 Rare-Earth Fluoride Nanotubes ......................... 110 8.8 Conclusion ............................................ 113 References ................................................. 114 Index ...................................................... 114 9 Synthesis and Applications of Zirconia and Ruthenium Oxide Nanotubes Mitsunori Yada and Yuko Inoue .............................. 117 9.1 Zirconia Nanotubes .................................... 117 9.1.1 Introduction ................................... 117 9.1.2 Zirconia Nanotubes Synthesized Using Carbon Nanotubes or Nanofibers as Templates ........... 118 9.1.3 Zirconia Nanotube Arrays Synthesized by Anodization of Metal Zirconium ................. 121 9.1.4 Zirconia Nanotubes Synthesized Using a Porous Membrane as a Template ......................... 121 9.1.5 Zirconia Nanotubes Synthesized Using a One-Dimensional Assembly Formed by Amphipathic Molecules as a Template ............ 126 9.2 Ruthenium Oxide Nanotubes ............................. 126 9.2.1 Introduction ................................... 126 9.2.2 Ruthenium Oxide and Ruthenium Oxide Hydrate Nanotubes Synthesized Using Anodic Porous Alumina Membrane ............................... 127 9.2.3 Ruthenium Compound Nanotubes Templated by Surfactant Assemblies ....................... 130 9.3 Conclusion ............................................ 131 References ................................................. 132 Index ...................................................... 132 10 Conversion of Metal Oxide Nanosheets into Nanotubes Renzhi Ma and Takayoshi Sasaki ............................. 135 10.1 Nanosheet and Nanotube ................................ 135 10.2 Spontaneous Conversion of Nanosheets into Nanotubes During Exfoliation of Certain Layered Oxides .......... 138 10.3 Conversion of Nanosheets into Nanotubes via a Designed Soft Chemical Procedure .................... 141 10.4 Summary ............................................... 144 References ................................................. 144 Index ...................................................... 145 11 Synthesis and Applications of Mixed Oxide Nanotubes Hitoshi Ogihara, Masahiro Sadakane, and Wataru Ueda ........ 147 11.1 Conventional Fabrication Processes for Mixed Oxide Nanotubes ....................................... 147 11.2 Synthesis of Mixed Oxide Nanotubes Using Carbon Nanofibers as Templates ............................... 149 11.3 Synthesis of Macro-Nanostructured Materials Using Template Method ....................................... 152 11.4 Application of Macro-Nanostructured Materials to Catalytic Systems ..................................... 155 11.5 Summary ............................................... 156 References ................................................. 157 Index ...................................................... 157 12 Synthesis and Applications of Imogolite Nanotubes Masaya Suzuki and Keiichi Inukai ........................... 159 12.1 Introduction .......................................... 159 12.2 Synthesis of Imogolite ................................ 160 12.2.1 Synthesis Method ............................... 160 12.2.2 Influence of Heating Temperature and Elemental Substitution ......................... 163 12.3 Application of Imogolite .............................. 163 12.3.1 Anti-dewing Material ........................... 163 12.3.2 Heat Exchange Material in Adsorption-Type Heat Pump Systems .............................. 165 12.4 Possible Future Problems .............................. 166 References ................................................. 166 Index ...................................................... 167 13 Structure and Properties of Imogolite Nanotubes and Their Application to Polymer Nanocomposites Hideyuki Otsuka and Atsushi Takahara ....................... 169 13.1 Introduction .......................................... 169 13.2 Natural Imogolite Nanotubes ........................... 171 13.3 Chemical Synthesis of Imogolite Nanotubes ............. 172 13.4 Structure of Imogolite Nanotubes ...................... 173 13.5 Chemical and Physical Properties of Imogolite Nanotubes ............................................. 175 13.6 Hybrid Materials Using Imogolite Nanotubes ............ 176 13.6.1 Surface Modification of Imogolite Nanotubes .... 176 13.6.2 Polymer Hybrids with Imogolite Nanotubes ....... 178 13.6.3 Imogolite Nanotubes as Templates ............... 186 13.7 Concluding Remarks .................................... 187 References ................................................. 187 Index ...................................................... 189 14 Synthesis and Applications of Chalcogenide Nanotubes Tsukio Ohtani .............................................. 191 14.1 Introduction .......................................... 191 14.2 Transition-Metal Dichalcogenides with Layered Structures ............................................ 192 14.3 Chalcogenide Nanotubes (ChNTs) ........................ 193 14.3.1 Formation Mechanism of MS2 (M = W, Mo) Nanotubes ...................................... 193 14.3.2 Preparation of Different Chalcogenide Nanotubes (ChNTs)............................... 194 14.3.3 Properties and Applications of Chalcogenide Nanotubes (ChNTs) .............................. 197 References ................................................. 198 Index ...................................................... 199 15 Synthesis and Functions of Fullerene Nanotubes Kun Hchi Miyazawa .......................................... 201 15.1 Introduction .......................................... 201 15.2 Liquid-Liquid Interfacial Precipitation Method ........ 202 15.3 Synthesis and Properties of Fullerene Nanotubes ....... 205 15.4 Summary ............................................... 212 References ................................................. 213 Index ...................................................... 214 16 Synthesis and Applications of Noble-Metal Nanotubes Tsuyoshi Kijima ............................................ 215 16.1 Introduction .......................................... 215 16.2 Template-Free Synthesis of Base Metal Nanotubes ....... 217 16.3 Synthesis of Noble-Metal Nanotubes Using Solid Templates ............................................. 219 16.4 Synthesis of Noble-Metal Nanotubes Using Molecular Templates ............................................. 221 16.4.1 Mixed Surfactant LC Templating Approach to Noble-Metal and Other Nanostructures Using Single- and Triple-Branched PEO-Type Surfactants .................................... 221 16.4.2 Synthesis of Silver Nanotubes Using Mixed Surfactant LC Templating Methods ............... 222 16.4.3 Synthesis of Platinum and Palladium Nanotubes Using Mixed Surfactant LC Templating Methods ... 223 16.5 Applications of Noble-Metal Nanotubes ................. 229 16.6 Concluding Remarks .................................... 231 References ................................................. 231 Index ...................................................... 234 17 Synthesis and Applications of Magnetic-Metal Nanotubes Masaru Nakagawa, Hirokazu Oda, and Kei Kobayashi ........... 235 17.1 Introduction .......................................... 235 17.2 Template Synthesis of Nickel-Containing Tubular Materials by Electroless Deposition ................... 236 17.3 Application to an Anisotropic Conduction Film ......... 239 17.3.1 Filler-Orientation-Type Anisotropic Conduction Film ................................ 241 References ................................................. 244 Index ...................................................... 246 18 Synthesis and Applications of Water Nanotubes Yutaka Maniwa and Hiromichi Kataura ........................ 247 18.1 Introduction .......................................... 247 18.2 Water Containing Carbon Nanotube ...................... 248 18.3 Liquid-Solid Phase Transition: Formation of Ice Nanotube .............................................. 250 18.4 Computer Simulations of Ice Nanotube .................. 254 18.5 Physical Properties and Application of Water Containing SWCNT ...................................... 256 References ................................................. 258 Index ...................................................... 259 19 Design and Synthesis of Titanium Oxide Nanotubes Akira Hasegawa ............................................. 261 19.1 Introduction .......................................... 261 19.2 Crystal Structure Models and Electronic Structure Model Calculation ..................................... 262 19.3 Highly Functional Nanotube: Conductivity Grant = Reduction of Resistivity .............................. 265 19.4 Crystal Structure and Electric Conductive Property of Titanium Oxide ..................................... 267 19.5 Synthesis of Titanium Oxide Nanotubes ................. 268 19.6 Concluding Remarks .................................... 271 References ................................................. 272 Index ...................................................... 272 20 In Situ ТЕМ Electrical and Mechanical Probing of Individual Multi-walled Boron Nitride Nanotubes Dmitri Golberg, Pedro M.F.J. Costa, Masanori Mitome, and Yoshio Bando ........................................... 275 20.1 Introduction .......................................... 275 20.2 Electrical Probing Experiments ........................ 275 20.2.1 Unfilled Multi-walled BN Nanotubes ............. 275 20.2.2 Filled BN Nanotubes ............................ 278 20.3 Mechanical Probing of BN Nanotubes .................... 281 20.4 Summary ............................................... 284 References ................................................. 284 Index ...................................................... 285 Index ......................................................... 287