Stereoselective Synthesis 2:
Stereoselective Reactions of Carbonyl and Imino Groups
Preface .................................................... V
Volume Editors' Preface .................................. VII
Abstracts ................................................. XI
Table of Contents ...................................... XXIII
Introduction
C.A. Molander .............................................. 1
2.1 Reduction of Carbonyl Croups: Hydrogenation
N. Arai and T. Ohkuma ...................................... 9
2.2 Reduction of Carbonyl Croups: Transfer Hydrogenation,
Hydrosilylation, Catalytic Hydroboration, and Reduction
with Borohydrides, Aluminum Hydrides, or Boranes
M. Zaidlewicz and M.M. Pakulski ........................... 59
2.3 Enzymatic Reduction of Carbonyl Croups
S. De Wildeman and N. Sereinig ........................... 133
2.4 Oxidative Deracemization
B. Stoltz, D.C. Ebner, and N. Park ....................... 209
2.5 Stereoselective Reduction of Imino Croups
L. Xu, X. Wu, and J. Xiao ................................ 251
2.6 Epoxidation and Aziridination of Carbonyl Croups
and Imines
V.K. Aggarwal, E.M. McGarrigle, and M.A. Shaw ............ 311
2.7 Alkylation of Carbonyl and Imino Croups
D.J. Ramon and M. Yus .................................... 349
2.8 Allylation of Carbonyl and Imino Croups
A. Buitrago Santanilla and J.L. Leighton ................. 401
2.9 Arylation and Alkenylation of Carbonyl and Imino Croups
M.C. Kauffman and P.J. Walsh ............................. 449
2.10 Alkynylation of Carbonyl and Imino Croups ................ 497
2.10.1 Enantioselective Addition of Acetylide
Nucleophiles to Carbonyl Compounds
E.M. Carreira and D.E. Frantz ..................... 497
2.10.2 Enantioselective Addition of Metal Alkynylides
to Imino Croups
E.M. Carreira and P. Aschwanden ................... 517
2.11 Hydrocyanation, Cyanosilylation, and
Hydrophosphonylation of Carbonyl and Imino Croups
E. Bergin ................................................ 531
2.12 Asymmetric Mukaiyama Aldol Reaction
L. Liu, D. Wang, and C.-J. Li ............................ 585
2.13 Direct Aldol Reactions
S.M. Yliniemelä-Sipari and P.M. Pihko .................... 621
2.14 Enzymatic Direct Aldol Additions
P. Gapés and W.-D. Fessner ............................... 677
2.15 Asymmetric Morita-Baylis-Hillman Reaction and Its Aza
Analogue
C. Masson and J. Zhu ..................................... 735
2.16 Mannich Reaction
N.Z. Burns and E.N. Jacobsen ............................. 785
2.17 Asymmetric Benzoin and Stetter Reactions
D.A. DiRocco and T. Rovis ................................ 835
2.18 Asymmetric Synthesis of Spiroketals, Bisspiroketals,
and Spiroaminals
R.G. Carter and D.L. Kuiper .............................. 863
Keyword Index ............................................ 915
Author Index ............................................. 967
Abbreviations ........................................... 1011
|
