Organic materials for sustainable construction (London, 2011). - ОГЛАВЛЕНИЕ / CONTENTS
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ОбложкаOrganic materials for sustainable construction / ed. by Y.Mouton. - London: ISTE; Hoboken: Wiley, 2011. - xxviii, 651 p.: ill. - Ind.: p.649-651. - ISBN 978-1-84821-224-4
 

Оглавление / Contents
 
Introduction ................................................ xxiii
Yves Mouton

Part 1  Problems Regarding Organic Materials and
        Sustainable Development ................................. 1

Chapter 1  Organic materials used in Construction at the Dawn
           of the Third Millennium .............................. 3
           Michel de Longcamp and Yves Mouton
1.1  Specifically polymer-based products ........................ 5
     1.1.1  Plastics, rubbers and geosynthetics ................. 5
     1.1.2  Resins, coatings, paintings ......................... 8
     1.1.3  Incorporated components: organic fiber and
            concrete adjuvants ................................. 10
1.2  Bitumen and related products .............................. 10
1.3  Organic matrix composite  ................................. 11
1.4  Timber .................................................... 12
1.5  Conclusion ................................................ 13
1.6  Bibliography .............................................. 13
     
Chapter 2  Sustainable Development Issues Regarding Organic
           Materials used in Civil Engineering ................. 15
           Agnes Jullien
2.1  Introduction .............................................. 15
2.2  Sustainable development: definitions, general issues
     and issues in construction ................................ 16
     2.2.1  The political concept .............................. 16
     2.2.2  Possible actions ................................... 17
     2.2.3  Environmental considerations ....................... 18
     2.2.4  Towards normative reference - certification of
            construction works ................................. 21
2.3  Civil engineering materials in their environment .......... 23
     2.3.1  Organic materials development practices ............ 23
     2.3.2  From resources to construction: matter
            transformation ..................................... 24
     2.3.3  Durability: the unquestionable effect of time ...... 25
     2.3.4  About material lifecycle ........................... 25
2.4  Sustainable development and civil engineering ............. 28
     2.4.1  Links between study domains of material and
            construction work .................................. 28
     2.4.2  Temporal and spatial scales to be taken into
            account for the environment ........................ 30
     2.4.3  Environmental assessment of materials lifecycle
            of ................................................. 32
2.5  Conclusion ................................................ 34
2.6  Bibliography .............................................. 34
     
Chapter 3  Health Risks of Organic Materials used in
           Construction:  What is the Situation Today? ......... 37
           Guy Auburtin
3.1  Problems concerning the health risks, and available
     tools ..................................................... 37
3.2  Available data in organic construction materials .......... 41
     3.2.1  State of knowledge on the risks related to
            bitumens ........................................... 41
     3.2.2  Quality of inside air and health qualification
            of construction materials .......................... 44
3.3  Conclusion ................................................ 46
3.4  Bibliography .............................................. 47

Chapter 4  Ecological Impacts of Organic Construction
           Materials: What is the Situation Today? ............. 51
           Yves Perrodin
4.1  Problems and available tools .............................. 51
4.2  Works available in the field of organic construction
     materials ................................................. 54
4.3  Prospects for organic materials used in construction ...... 56
4.4  Conclusion ................................................ 58
4.5  Bibliography .............................................. 58
4.6  For more information ...................................... 59

Part 2  Organic Polymers as Building Materials ................. 63

Chapter 5  Organic Polymers .................................... 65
           Jacques Verdu and Bruno Fayolle
5.1  Introduction .............................................. 65
     5.1.1  Brief history ...................................... 65
     5.1.2  Polymers among materials ........................... 66
5.2  Polymer structures ........................................ 69
     5.2.1  Three structure scales ............................. 69
     5.2.2  Molecular structure ................................ 70
     5.2.3  Order in the chain - copolymers, stereoisomers,
            conformations ...................................... 74
     5.2.4  Macromolecular architectures: thermoplastics and
            thermosets ......................................... 78
     5.2.5  Structure on a macromolecular scale ................ 80
     5.2.6  Structure on a supramolecular scale ................ 86
5.3  Additives and fillers ..................................... 94
     5.3.1  Additives .......................................... 94
     5.3.2  Fillers ............................................ 95
5.4  Processing properties ..................................... 96
     5.4.1  Thermoplastics ..................................... 96
     5.4.2  Thermosetting polymers ............................. 98
5.5  Mechanical properties ..................................... 99
     5.5.1  Elastomers ......................................... 99
     5.5.2  Mechanical properties of glassy amorphous
            polymers .......................................... 103
     5.5.3  Mechanical properties of semi-crystalline
            polymers .......................................... 109
5.6  Plasticizers and impact modifiers ........................ 112
     5.6.1  Plasticizers ...................................... 112
     5.6.2  Impact modifiers .................................. 114
5.7  Properties of a few industrial linear polymers ........... 117
5.8  Conclusion ............................................... 118
5.9  Bibliography ............................................. 119
5.10 More information ......................................... 120

Chapter 6  Formulation of Plastics ............................ 121
           Michel de Longcamp
6.1  Introduction ............................................. 121
6.2  Ingredients used for plastic formulation ................. 123
     6.2.1  Polymers .......................................... 123
     6.2.2  Working agents .................................... 123
     6.2.3  Cross-linking agents .............................. 124
     6.2.4  Stabilizers ....................................... 124
     6.2.5  Plasticizers, non-working agents .................. 126
     6.2.6  Various organic additives ......................... 127
     6.2.7  Fillers ........................................... 129
6.3  Conclusion ............................................... 129

Chapter 7  Ageing and Durability of Organic Polymers .......... 131
           Jacques Verdu and Bruno Fayolle
7.1  Definitions, general comments ............................ 131
     7.1.1  Ageing ............................................ 131
     7.1.2  Lifetime .......................................... 131
     7.1.3  Extrapolation principle ........................... 132
     7.1.4  Induction period .................................. 133
     7.1.5  Different types of ageing ......................... 135
7.2  Physical ageing .......................................... 135
     7.2.1  Physical ageing by structural relaxation (broad
            meaning) .......................................... 135
     7.2.2  Ageing by solvent absorption ...................... 138
     7.2.3  Ageing by additive migration ...................... 139
7.3  Chemical ageing - general aspects ........................ 143
     7.3.1  The two large families of chemical ageing
            processes ......................................... 143
     7.3.2  Diffusional phenomena in chemical ageing .......... 148
     7.3.3  Towards a non-empirical lifetime prediction ....... 153
     7.3.4  Oxidation - general aspects ....................... 154
     7.3.5  Stabilization ..................................... 157
7.4  Thermochemical ageing .................................... 159
     7.4.1  Intrinsic thermal stability ....................... 159
     7.4.2  Oxidative ageing .................................. 161
     7.4.3  Lifetime in thermal ageing ........................ 162
7.5  Photochemical ageing ..................................... 164
     7.5.1. Introduction: solar radiation ..................... 164
     7.5.2  "Intrinsic" photochemistry and photo-oxidation;
            photo-oxidation and thermo-oxidationthermo-
            oxidation ......................................... 165
     7.5.3  Photostabilisation. UV screens .................... 167
     7.5.4  Towards a lifetime prediction in photoageing ...... 168
7.6  Hydrolytic ageing ........................................ 169
     7.6.1  Introduction ...................................... 169
     7.6.2  Quasi-irreversible hydrolysis ..................... 170
     7.6.3  Reversible hydrolysis ............................. 172
     7.6.4  Role of solutes in water .......................... 173
     7.6.5  Secondary effects of hydrolysis: composites ....... 174
     7.6.6  Stabilization ..................................... 175
7.7  Conclusion ............................................... 176
7.8  Bibliography ............................................. 177
7.9  More information ......................................... 177

Chapter 8  Fireproofing polymeric materials: problems and
           solutions .......................................... 179
           Serge Bourbigot
8.1  Introduction ............................................. 179
8.2  Combustion principles .................................... 181
8.3  Action in gas phase ...................................... 182
8.4  Cooling and ceramization ................................. 183
8.5  The concept of intumescence .............................. 184
8.6  Nanocomposites ........................................... 184
8.7  Intumescent coatings for protecting steel ................ 185
8.8  Conclusion ............................................... 187
8.9  Bibliography ............................................. 187
8.10 For more information ..................................... 188

Chapter 9  Organic Materials, Waste and Recycling ............. 189
           Vincent Verney
9.1  Introduction ............................................. 189
9.2  Assessment ............................................... 190
     9.2.1  Definitions ....................................... 190
     9.2.2  Plastics: facts and figures ....................... 191
     9.2.3  Legislation ....................................... 193
     9.2.4  Recycling and valorization channels ............... 194
     9.2.5  Current proportion of recycling in waste
            disposal .......................................... 195
9.3  Scientific aspects ....................................... 197
     9.3.1  The concept of lifecycle .......................... 197
     9.3.2  Concept of adequacy, application duration/
            lifetime durability ............................... 198
9.4  The construction sector .................................. 199
9.5  Conclusion ............................................... 201
9.6  Bibliography ............................................. 201

Part 3  Manufactured Products ................................. 203

Chapter 10 Geosynthetics and Waterproofing .................... 205
           Philippe Mestat
10.1 Waterproofing in civil engineering ....................... 205
10.2 Flow in civil engineering materials ...................... 208
     10.2.1 Equations of porous media mechanics ............... 208
     10.2.2 Permeability coefficients ......................... 210
10.3 Characteristics of infiltration liquids .................. 213
10.4 Choice of waterproofing device ........................... 214
10.5 Advantages of geosynthetics .............................. 216
     10.5.1 Geosynthetic types ................................ 216
     10.5.2 Geosynthetics and their function in
            constructions ..................................... 216
     10.5.3 Reinforcement and protection function of
            geosynthetics ..................................... 220
     10.5.4 Hydraulic performances of geosynthetics ........... 223
     10.5.5 Geosynthetic drainage functions ................... 225
10.6 Waterproofing functions of geosynthetics ................. 226
     10.6.1 Geocomposite and geomembrane clay liners .......... 226
     10.6.2 Geomembranes ...................................... 226
     10.6.3 Synthetic geomembranes ............................ 227
     10.6.4 Bituminous geomembranes ........................... 229
     10.6.5 Geosynthetic clay liners .......................... 229
10.7 Geosynthetics layering in construction ................... 232
     10.7.1 Assembling geosynthetic layers .................... 232
     10.7.2 Connecting geosynthetic layers to constructions ... 235
     10.7.3 Stability of geosynthetic fabrics on slopes ....... 236
10.8 Product specificity and waterproofing systems ............ 237
     10.8.1 Composition of geosynthetic waterproofing
            devices (DEG) ..................................... 237
     10.8.2 Composition of a draining system with
            geosynthetics (DDG) ............................... 239
     10.8.3 Composition of a waterproofing and drainage
            system with geosynthetics (DEDG) .................. 239
     10.8.4 Composition of a waterproofing device by
            geosynthetic clay liners (DEGB) ................... 241
     10.8.5 Analysis and dimensioning of geosynthetic based
            structures ........................................ 242
10.9 Numerical modeling ....................................... 242
     10.9.1 Mechanical behavior ............................... 242
     10.9.2 Mechanical behavior modeling by finite elements ... 244
     10.9.3 Numerical modeling of hydraulic behavior .......... 247
10.10 Sustainability .......................................... 250
10.11 Testing, exploitation, maintenance, repair .............. 252
     10.11.1 Levels of testing ................................ 252
     10.11.2 Evidence of loss of waterproofing ................ 253
     10.11.3 Methods for detecting defects .................... 255
     10.11.4 Repairing constructions and autocicatrization .... 256
10.12 Watertight barriers for waste storage sites ............. 257
     10.12.1 Designing a waste storage site ................... 257
     10.12.2 Foundation of a waste storage site ............... 259
     10.12.3 Waste storage site slope ......................... 259
     10.12.4 Waste storage site covers ........................ 260
     10.12.5 Using geosynthetic materials in waste storage
             sites ............................................ 260
     10.12.6 Numerical modeling of waste storage sites ........ 261
10.13 Conclusions and perspectives ............................ 262
10.14 Bibliography ............................................ 263
10.15 More information ........................................ 267

Chapter 11 Waterproofing Buildings: The Point of View of
           an Expert .......................................... 269
           Gerard Hémond
11.1 Introduction ............................................. 269
11.2 Initial analyses ......................................... 270
11.3 Initial obligations ...................................... 272
11.4 Questions of definition .................................. 272
11.5 Possible solutions ....................................... 273
     11.5.1. Watertight concrete .............................. 274
     11.5.2 Mineral products .................................. 275
     11.5.3 "Black" products .................................. 275
     11.5.4 Organic and synthetic materials ................... 276
     11.5.5 Complementary products: expansion joints .......... 280
11.6 The future of these recent technologies .................. 282
     11.6.1 Products .......................................... 282
     11.6.2 Applicators ....................................... 282

Chapter 12 Elastomers and Rubbers used in Civil
           Engineering ........................................ 283
           Michel Fragnet
12.1 Introduction ............................................. 283
     12.1.1 Elastomers ........................................ 283
     12.1.2 The products in question: field presentation ...... 286
     12.1.3 Terminology and vocabulary peculiar to this
            field ............................................. 287
12.2 Bearings ................................................. 288
     12.2.1 Role and functions of bearings .................... 288
     12.2.2 Historical background ............................. 289
     12.2.3 Laminated or strip elastomeric bearings ........... 290
     12.2.4 Elastomeric pot bearings .......................... 295
     12.2.5 Bearings with polyurethane discs .................. 298
12.3 Expansion joints ......................................... 298
     12.3.1 Role and function of a road bridge expansion
            joint ............................................. 298
     12.3.2 The various product families ...................... 301
     12.3.3 Method of elaboration, manufacturing principle .... 302
     12.3.4 Advantages and limitations: durability ............ 303
12.4 Sealingv joints ........................................... 304
12.5 Bridges deck waterproofing ............................... 306
     12.5.1 Role and function of a waterproofing .............. 306
     12.5.2 The various family products. Method of
            elaboration and fabrication ....................... 306
     12.5.3 Advantages and limits: durability ................. 307
12.6 Anti-seismic devices ..................................... 308
12.7 General reflections on sustainable development ........... 309
12.8 Conclusions .............................................. 310
12.9 Acknowledgements ......................................... 310
12.10 Bibliography ............................................ 311

Part 4  Composite Materials, Tensile Structures, Textile
        Architecture and Timber ............................... 313

Chapter 13 Composite Materials and Construction ............... 315
           Jean-François Caron
13.1 Introduction ............................................. 315
13.2 Composites used in construction .......................... 317
     13.2.1 General remarks ................................... 317
     13.2.2 Fibers ............................................ 317
     13.2.3 Different available fiber architecture ............ 320
     13.2.4 Matrices .......................................... 320
     13.2.5 Transformation processes and semi-products for
            construction ...................................... 321
13.3 Applications today ....................................... 322
     13.3.1 Pre-stressing and cable staying in composite
            materials ......................................... 323
     13.3.2 Bars for reinforced concrete ...................... 324
     13.3.3 Composite beams for crossing ...................... 325
     13.3.4 Composite bridge decks ............................ 325
     13.3.5 Sandwich roofs .................................... 326
     13.3.6 Some examples of constructions .................... 326
13.4 Perspectives and projects ................................ 328
     13.4.1 Composite crossings and footbridges ............... 329
     13.4.2 Composite gridshells .............................. 332
13.5 Recommendations, norms and standards ..................... 334
     13.6 Composites and the environment: reflections ......... 335
     13.7 Conclusion .......................................... 336
     13.8 Bibliography ........................................ 336

Chapter 14 Textile Materials: Architectural Applications ...... 339
           Bernard Maurin and Romain Ferrari
14.1 Introduction ............................................. 339
14.2 Architectural textile membranes .......................... 340
     14.2.1 Different fabric types ............................ 340
     14.2.2 Conceptual design ................................. 341
14.3 Tensile membranes engineering ............................ 343
     14.3.1 Two keywords: curvature and pretension ............ 343
     14.3.2 Form-finding ...................................... 344
     14.3.3 Behavior under external loads ..................... 345
     14.3.4. Fabric patterning ................................ 346
14.4 Eco-design in textile architecture ....................... 347
     14.4.1 Fabric recycling .................................. 347
     14.4.2 Thermal aspects ................................... 349
14.5 Conclusion and perspectives .............................. 350
14.6 Bibliography ............................................. 351

Chapter 15 Wood ............................................... 353
           Rémy Mouterde
15.1 From the thinkable, to the possible ...................... 354
15.2 Biological structure ..................................... 355
     15.2.1 Growth ............................................ 356
     15.2.2 From the plank to the molecules ................... 357
     15.2.3 Composition ....................................... 360
     15.2.4 Characteristics of physical behavior .............. 363
15.3 Industrial approach of material .......................... 371
     15.3.1 Improvement of natural material ................... 371
     15.3.2 Derivative products ............................... 374
     15.3.3 Evolution of the glues ............................ 380
     15.3.4 Developments in constructive technologies ......... 381
15.4 Conclusion ............................................... 385
     15.5 Bibliography ........................................ 386
     15.6 More information .................................... 386

Part 5  Organic Binder-based Materials ........................ 389

Chapter 16 Bitumen, Road Construction and Sustainable
           Development ........................................ 391
           Bernard Lombardi
16.1 A bit of history ......................................... 391
     16.1.1 An ancient history ................................ 391
     16.1.2 First definitions ................................. 392
     16.1.3 Bitumen in contemporary times ..................... 393
     16.1.4 Bitumen in road engineering ....................... 393
16.2 Bitumen and bitumen binders today ........................ 395
     16.2.1 Manufacturing bitumen ............................. 395
     16.2.2 Bitumen composition ............................... 396
     16.2.3 Simple characterization of bitumen ................ 397
16.3 Bitumen, environment and health. REACH regulation ........ 399
     16.3.1 Relating to the REACH regulation .................. 399
     16.3.2 Bitumen and the REACH regulation .................. 400
     16.3.3 Bitumen and hygiene, safety and the environment ... 401
16.4 Bitumen and sustainable development ...................... 403
16.5 Conclusion ............................................... 404
16.6 Bibliography ............................................. 405
16.7 More information ......................................... 405

Chapter 17 Industrial Mortars and Repairing Concrete
           Products ........................................... 407
           Pierre Boulanger and Paulo Goncalo
17.1 Definitions .............................................. 407
17.2 The contribution of organic compounds in formulating
     industrial mortars ....................................... 408
     17.2.1 Contributions for usage ........................... 408
     17.2.2 Contributions for expected performances ........... 410
17.3 Repairing concretes ...................................... 413
     17.3.1 Norm EN 1504 ...................................... 413
     17.3.2 Implementation of repair strategies ............... 414
     17.3.3 Families repair products .......................... 417
17.4 Conclusion ............................................... 418
17.5 For more information ..................................... 418

Chapter 18 Waterborne Paints to Limit VOC Emissions:
           Interests and Limits ............................... 419
           Emmanuel Aragon and André Margaillan
18.1 Introduction ............................................. 419
18.2 Definition of paint ...................................... 420
18.3 Main features and properties of waterborne paints ........ 421
     18.3.1 History of the development of waterborne paints ... 421
     18.3.2 Various types of paint in aqueous phase ........... 421
     18.3.3 Film formation process ............................ 422
     18.3.4 Various product families .......................... 422
18.4 Advantages and disadvantages for using water as a
     solvent .................................................. 423
     18.4.1 Advantages ........................................ 423
     18.4.2 Disadvantages ..................................... 424
     18.4.3 Health and safety hazards ......................... 426
     18.4.4 Conclusion ........................................ 426
18.5 Advantages and disadvantages of using water-based
     paints in relation to alternative solutions .............. 427
     18.5.1 Powder coatings ................................... 427
     18.5.2 Radiation curing paints ........................... 427
     18.5.3 High solids paints ................................ 428
18.6 Conclusion: the need for an eco-assessment ............... 428
18.7 Bibliography ............................................. 429

Part 6  Organic Compounds Built-in into Cement Matrices ....... 431

Chapter 19 Rheological Admixtures ............................. 433
           Nicolas Roussel
19.1 History of rheological admixtures ........................ 433
19.2 Macroscopic behavior and microscopic interactions in a
     cementitious suspension .................................. 435
     19.2.1 Components and composition of cement
            suspensions ....................................... 436
     19.2.2 Distant inter-particle interactions ............... 437
     19.2.3 Contact type interactions ......................... 441
     19.2.4 Hydrodynamic effects .............................. 442
19.3 Conclusion ............................................... 444
19.4 Bibliography ............................................. 445

Chapter 20 Contributions of Organic Admixtures in
           Construction Processes ............................. 447
           François Cussigh
20.1 Introduction ............................................. 447
20.2 The situation without the contribution of organic
     chemistry ................................................ 447
20.3 Contribution of superplasticizers ........................ 448
20.4 Example of pre-stressed grouting ......................... 448
20.5 High performance concretes (HPC) ......................... 449
20.6 Self-compacting concretes ................................ 450
20.7 Ultra-high performance fiber reinforced concrete
     (UHPFC) .................................................. 453
20.8 Currently used concretes ................................. 454
20.9 Perspectives ............................................. 454
20.10 Bibliography ............................................ 455

Chapter 21 Organic Fibers in Cementitious Materials ........... 457
           Laetitia d'Aloia-Schwartzentruber
21.1 Introduction ............................................. 457
     21.1.1 Characteristics of main fibers .................... 458
     21.1.2 Fiber reinforced cement material, application in
            civil engineering ................................. 459
21.2 The use of organic fibers in cementitious materials ...... 460
     21.2.1 The contribution of organic fibers ................ 460
     21.2.2 The most used organic fibers in cementitious
            materials ......................................... 461
     21.2.3 Organic fiber/cement material composite ........... 462
21.3 A return to the use of some organic fibers ............... 463
     21.3.1 Polypropylene fibers .............................. 463
     21.3.2 Plant fibers ...................................... 472
21.4 Contribution of organic fibers to recycling .............. 475
21.5 Conclusion ............................................... 476
21.6 Bibliography ............................................. 478

Part 7  Problems Specific to Organic Materials: Adhesive
        Bonding and Characterization Methods .................. 483

Chapter 22 Adhesive Bonding, a Method for Construction ........ 485
           Thierry Chaussadent
22.1 Preliminary thoughts ..................................... 485
22.2 Introduction ............................................. 486
22.3 Theory of adhesion and practical conclusions ............. 487
     22.3.1 Microscopic aspects of adhesion ................... 487
     22.3.2 Macroscopic aspects. Adhesive strength and
            mechanical properties of adhesive bonds ........... 489
22.4 Adhesive formulation and implementation .................. 491
     22.4.1 Adhesives used in construction .................... 491
     22.4.2 Implementation of adhesion techniques ............. 492
22.5 Ageing of adhesive bonds ................................. 494
     22.5.1 Microscopic aspects ............................... 495
     22.5.2 Macroscopic aspects ............................... 496
22.6 Paths for progress in the development of adhesive
     bonding techniques in civil engineering .................. 497
     22.6.1 Limitation of mechanical stresses ................. 497
     22.6.2 Adhesive choice and implantation management ....... 498
     22.6.3. Predicting durability and in situ monitoring ..... 499
22.7 Conclusion ............................................... 499
22.8 Bibliography ............................................. 500

Chapter 23 Strengthening Concrete Structures by Externally
           Bonded Composite Materials ......................... 503
           Marc Cuiertant
23.1 Introduction ............................................. 503
23.2 Composite materials for repairing and strengthening
     concrete structures ...................................... 505
23.3 History and background of structural strengthening
     techniques by externally bonded composites ............... 509
23.4 Mechanics of externally bonded FRP ....................... 510
     23.4.1 Flexural strengthening ............................ 510
     23.4.2 Shear strengthening ............................... 514
     23.4.3 Strengthening of compression elements ............. 516
23.5 Installation of FRP strengthening systems ................ 519
     23.5.1 Control of the strength of the concrete
            substrate ......................................... 519
     23.5.2 Surface preparation ............................... 520
     23.5.3 FRP installation .................................. 521
     23.5.4 Finishing or protective coats ..................... 524
23.6 Conclusion. Future of strengthening concrete structures
     by externally bonded composite materials ................. 524
23.7 Bibliography ............................................. 525

Chapter 24 Durability of FRP Strengthened Concrete Specimens
           under Accelerated Ageing ........................... 529
           Karim Benzarti, Marc Quiertant, Sylvain
           Chataigner and Christophe Aubagnac
24.1 Introduction ............................................. 529
24.2 Experimental results and discussions ..................... 530
     24.2.1 First set of experiments: Investigation on FRP
            strengthened concrete slabs using the pull-off
            test .............................................. 530
     24.2.2 Second set of experiments: Investigation on FRP
            strengthened concrete blocks using both the
            pull-off test and the single lap shear test ....... 537
24.3 Conclusion ............................................... 550
24.4 Acknowledgements ......................................... 550
24.5 Bibliography ............................................. 550

Chapter 25 Characterization of Organic Materials used in
           Civil Engineering by Chemical and Physico-
           chemical Methods ................................... 553
           Fabienne Farcas
25.1 Bituminous binders ....................................... 553
     25.1.1 Pure bitumen ...................................... 554
     25.1.2 Special bitumens .................................. 559
     25.1.3 Polyphosphoric acid modified bitumens ............. 563
25.2 Anti-corrosive paints .................................... 565
     25.2.1 Ageing of chlorinated rubber binders .............. 566
     25.2.2 Ageing of polyurethane, urethane-acrylic and
            alkyd-urethane paint binders ...................... 569
25.3 Organic admixture in cementing materials ................. 572
     25.3.1 Evolution of "classic" superplasticizers in
            hardened cement pastes ............................ 572
     25.3.2 New generation admixtures ......................... 576
25.4 Conclusion ............................................... 578
25.5 Bibliography ............................................. 578

Part 8 Organic Materials, Construction, Architecture,
       Creation and Sustainable Development ................... 583

Chapter 26 Organic Materials and Sustainable Architectural
           Design ............................................. 585
           Michel Paulin
26.1 A context of accelerated evolution ....................... 585
     26.1.1 Post-war practices ................................ 585
     26.1.2 The first oil crisis .............................. 586
     26.1.3 New modernity and heritage ........................ 586
     26.1.4 The era for sustainable development ............... 587
26.2 New designer practices ................................... 588
     26.2.1 The revival of the systemic approach .............. 588
     26.2.2 Performance design ................................ 589
     26.2.3 Responsibility evolution .......................... 589
     26.2.4 Legal complexity .................................. 590
     26.2.5 NTIC on projects .................................. 590
26.3 New approaches to materials and structures ............... 591
     26.3.1. A new status for materials in society ............ 591
     26.3.2 The lack of image for organic materials ........... 591
     26.3.3 The specificity of composite materials ............ 592
     26.3.4 Double approach: low-tech and high-tech ........... 592
     26.3.5 Irruption of the nanoscopic scale ................. 593
26.4 What are the hopes for architectural creations? .......... 593
     26.4.1 Organic materials and the structure of the
            buildings ......................................... 594
     26.4.2 Organic materials for building enclosures ......... 595
     26.4.3 For the future? ................................... 597

Chapter 27 Specific Contributions of Viscous Behavior
           Materials in Construction .......................... 599
           Bernard Halphen
27.1 Introduction ............................................. 599
27.2 The viscosity of fresh concrete: a property to be taken
     into account ............................................. 600
27.3 Viscosity and inj ection products ........................ 602
27.4 Viscosity and self-repair ................................ 603
27.5 Viscosity and absorption ................................. 604
27.6 Conclusion ............................................... 607
27.7 Bibliography ............................................. 607

Chapter 28 Organics in Construction - How Far? ................ 609
           Henri Van Damme
28.1 A structured, decorated and communicating skin ........... 610
28.2 An energy collecting surface ............................. 611
28.3 A self-cleaning and depolluting envelope ................. 612
28.4 A self-repairing envelope ................................ 612
28.5 An air-conditioning envelope ............................. 613
28.6 Conclusion ............................................... 614
28.7 Bibliography ............................................. 615

Chapter 29 Thoughts on the Futurology in Research and
           Development of Innovative Materials ................ 617
           Jean Billard
29.1 Difficulty of prediction ................................. 617
29.2 The current state of things .............................. 618
29.3 Extrapolation attempts ................................... 619
     29.3.1 Primary resources ................................. 620
     29.3.2 Some social tendencies ............................ 621
     29.3.3 The complexity of technical systems ............... 621
     29.3.4 Research .......................................... 622
29.4 Futurology ............................................... 626
29.5 Conclusion ............................................... 627
29.6 Bibliography ............................................. 628

Conclusion .................................................... 631
     François Buyle-Bodin

Acronyms and Initials ......................................... 639

List of Authors ............................................... 645

Index ......................................................... 649


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Посещение N 1525 c 06.11.2012