Preface ........................................................ xi
1 The Interactions Affecting Organic Reactivity and
Selectivity in Ionic Liquids ................................. 1
Cinzia Chiappe, Daniela Pieraccini, and Christian Silvio
Pomelli
2 Electrophilic Chemistry in Ionic Liquids .................... 16
Kenneth K. Laali
3 Electropolymerization of Benzene in an Ionic Liquid ......... 28
F. Endres, N. Borissenko, and S. Zein El Abedin
4 Onium-Poly(Hydrogen Fluorides): Convenient Ionic Liquids
for Fluorination and Acid Catalysis ......................... 36
George A. Olah, G. K. Surya Prakash, and V. Prakash Reddy
5 Diels-AIder and Friedel-Crafts Reactions in Pyridinium-
Based Ionic Liquids ......................................... 58
Sanjay V. Malhotra and Ying Xiao
6 Organic Synthesis in Ionic Liquids Utilizing
Organometallic Reagents ..................................... 72
George W. Kabalka, Bollu Venkataiah, and Gang Dong
7 Transition Metal Complexes in Imidazolium Ionic Liquids
as Recoverable and Reusable Homogeneous Catalysts ........... 83
Hermenegildo García and Esther Carbonell
8 Approaches to Imino Diels-Alder Reactions in Imidazolium
Ionic Liquids ............................................... 95
Richard Kim, Ildiko Meracz, Laura Serbulea, Geronimo
Cebero, and Taeboem Oh
9 Synthesis of Homoallyl Ethers via Allylation of Acetals
and Aldehydes in Ionic Liquids ............................. 104
Ram S. Mohan and Peter W. Anzalone
10 Room Temperature Ionic Liquids as Homogeneous Supports
for Synthesis .............................................. 116
Scott T. Handy, Maurice Okello, and David Bwambok
11 Ionic Liquid as a Support of Organic and Inorganic
Catalysts .................................................. 127
Hisahiro Hagiwara
12 Ionic Liquids Applications in Green Chemistry: Copper and
Zinc Catalysis ............................................. 146
David L. Davies, Sukhvinder K. Kandola, and Raj K. Patel
13 Ionic Liquid: A Green Solvent for Organic
Transformations 1 .......................................... 161
Shui-Ling Chen, Guan-Leong Chua, Shun-Jun Ji, and Teck-
Peng Loh
14 Ionic Liquid: A Green Solvent for Organic
Transformations II ......................................... 177
Shui-Ling Chen, Guan-Leong Chua, Shun-Jun Ji, and Teck-
Peng Loh
15 Ionic Liquids: Neoteric Solvents for Organic and
Biocatalytic Transformations ............................... 194
Jitendra R. Harjani, Susheel J. Nara, Prashant U. Naik,
and Manikrao M. Salunkhe
16 Toward Green Processes for Fine Chemicals Synthesis:
Biocatalysis in Ionic Liquid-Supercritical Carbon Dioxide
Biphasic Systems ........................................... 209
Pedro Lozano, Teresa De Diego, Said Gmöuh, Michel
Vaultier, and Josée L. Iborra
17 Ruthenium Catalyzed Asymmetric Hydrogenation of α- and β-
Ketoesters in Room Temperature Ionic Liquids Using Chiral
P-Phos Ligand .............................................. 224
Lijin Xu, Kim Hung Lam, Jiwu Ruan, Qinghua Fan, and
Albert S.C. Chan
18 Organocatalyzed Asymmetric Michael Reaction in Ionic
Liquids-Carbon Dioxide ..................................... 235
João N. Rosa and Carlos A.M. Afonso
19 Enantiomerically Pure Thiazolinium and Imidazolium Low
Melting Point Salts Prepared from α-Aminoacids ............. 246
Delphine Brégeon, Jocelyne Levillain, Frãdãric Guillen,
Jean-Christophe Plaquevent, and Annie-Claude Gaumont
20 New Cations for Ionic Liquids, Including Chiral Adjuncts
with Phosphate and Sulfonylimide Anions .................... 259
Robert Engel, Sharon Lall-Ramnarine, Delroy Coleman, and
Marie Thomas
21 Tailoring Adsorption-Desorption Properties of
Hydroamination Catalysts with Ionic Liquids ................ 267
Oriol Jimenez, Thomas E. Müller, and Johannes A. Lercher
22 Synthesis and Application of New Ionic Liquids with
Tris(perfluoroalkyl)trifluorophosphate Anions .............. 281
N.V. Ignat'ev, W.-R. Pitner, and U. Welz-Biermann
Indexes
Author Index .................................................. 291
Subject Index ................................................. 293
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