Larina L. Nitroazoles: synthesis, structure and applications (Dordrecht; New York, 2009). - ОГЛАВЛЕНИЕ / CONTENTS
Навигация

Архив выставки новых поступлений | Отечественные поступления | Иностранные поступления | Сиглы
ОбложкаLarina L. Nitroazoles: synthesis, structure and applications / L.Larina, V.Lopyrev. - Dordrecht; New York: Springer, 2009. - xviii, 441 p.: ill. - (Topics in applied chemistry). - Incl. bibl. ref. - Ind.: p.435-441. - ISBN 978-0-387-98069-0
 

Место хранения: 054 | Международный томографический центр CO РАН | Новосибирск

Оглавление / Contents
 
Introduction ................................................... xv
Synthesis of Five-Membered Nitroazoles .......................... 1
Electrophilic Nitration of Azoles ............................... 1
   Electrophilic Nitration Mechanism ............................ 2
   Nitration with Nitric Acid or Sulfuric-Nitric Acid Mixture ... 5
   Kinetics and Mechanism of Nitration of Azoles
   by Sulfuric-Nitric Acid Mixture ............................. 21
   Nitration by Other Nitrating Agents ......................... 25
   Iрsо-Nitration of Azoles .................................... 32
Synthesis from Aminoazoles ..................................... 35
Synthesis Based on Heterocyclization ........................... 40
Synthesis from Various Cyclic Systems .......................... 49
Other Methods of Preparation ................................... 55
Polynitroazoles ................................................ 60
Conclusions .................................................... 64
References ..................................................... 64

Synthesis of Nitrobenzazoles ................................... 81
Introduction ................................................... 81
Nitration of Benzazoles ........................................ 82
   Indazoles ................................................... 82
   Benzimidazoles  ............................................. 84
   Benzisoxazoles, Benzoxazoles, and Benzoxadiazoles ........... 87
   Benzisothiazoles, Benzothiazoles, and Benzothiadiazoles ..... 91
   Benzoselenazoles and Benzoselenodiazoles .................... 93
   Benzotriazoles .............................................. 93
Synthesis of Nitrobenzazoles via Heterocyclization ............. 95
   Nitroindazoles .............................................. 95
   Nitrobenzimidazoles ........................................ 102
   Nitrobenzisoxazoles, Nitrobenzoxazoles, and 
   Nitrobenzoxadiazoles ....................................... 109
   Nitrobenzisothiazoles, Nitrobenzothiazoles,
   and Nitrobenzothiadiazoles ................................. 120
   Nitrobenzisoselenazoles, Nitrobenzoselenazoles,
   and Nitrobenzoselenodi azoles .............................. 130
   Nitrobenzotriazoles ........................................ 130
Other Methods of Synthesis .................................... 136
   The Sandmeyer Reaction ..................................... 136
   Recyclization .............................................. 137
Conclusions ................................................... 140
References .................................................... 141

Structure and Physical-Chemical Properties of Nitroazoles ..... 157
Molecular and Crystalline Structure ........................... 157
Nuclear Magnetic Resonance .................................... 181
   Pyrazoles .................................................. 182
   Imidazoles.................................................. 199
   Isoxazoles, Oxazoles, and Oxadiazoles ...................... 206
   Isothiazoles, Thiazoles, and Thiadiazoles .................. 215
   Triazoles and Tetrazoles ................................... 217
   Indazoles .................................................. 229
   Benzimidazoles ............................................. 236
   Benzoxazoles, Benzisoxazoles, and Benzofurazans ............ 245
   Benzothiazoles, Benzothiadiazoles, and Benzoselenazoles .... 253
   Benzotriazoles ............................................. 256
   Conclusions ................................................ 262
Electron Spin Resonance Spectroscopy .......................... 263
Polarography .................................................. 280
Infrared Spectroscopy ......................................... 295
   Nitropyrazoles ............................................. 295
   Nitroimidazoles ............................................ 297
   Nitroisoxazoles, Nitrooxazoles, and Nitrooxadiazoles ....... 298
   Nitroisothiazoles and Nitrothiazoles ....................... 300
   Nitrotriazoles ............................................. 302
   Nitrotetrazoles ............................................ 305
   Nitroindazoles ............................................. 305
   Nitrobenzimidazoles ........................................ 307
   Nitrobenzisoxazoles, Nitrobenzoxazoles, and 
   Nitrobenzoxadiazoles ....................................... 308
   Nitrobenzoselenodiazoles ................................... 310
   Nitrobenzothiazoles ........................................ 310
UV Spectroscopy ............................................... 310
   Nitropyrazoles ............................................. 310
   Nitroimidazoles ............................................ 313
   Nitroisoxazoles, Nitrooxazoles, and Nitrooxadiazoles ....... 316
   Nitroisothiazoles and Nitrothiazoles ....................... 317
   Nitrotriazoles ............................................. 318
   Nitrotetrazoles ............................................ 321
   Nitroindazoles ............................................. 321
   Nitrobenzimidazoles ........................................ 322
   Nitrobenzoxazoles and Nitrobenzoxadiazoles ................. 324
   Nitrobenzothiazoles and Nitrobenzothiadiazoles ............. 327
   Nitrobenzotriazoles ........................................ 328
Dipole Moments ................................................ 328
Mass Spectrometry ............................................. 332
   Nitropyrazoles ............................................. 332
   Nitroimidazoles ............................................ 336
   Nitroisoxazoles ............................................ 341
   Nitroisothiazoles, Nitrothiazoles, and Nitrothiadiazoles ... 345
   Nitrotriazoles and Nitrotetrazoles ......................... 346
   Nitroindazoles ............................................. 350
   Nitrobenzimidazoles ........................................ 352
   Nitrobenzisoxazoles, Nitrobenzoxazoles, and 
   Nitrobenzoxadiazoles ....................................... 357
   Nitrobenzoisothiazoles, Nitrobenzothiazoles,
   and Nitrobenzothiadiazoles ................................. 360
   Nitrobenzoselenodiazoles ................................... 360
   Nitrobenzotriazoles ........................................ 363
Conclusions ................................................... 364
Other Physical-Chemical Properties ............................ 364
References .................................................... 373

Application of Nitroazoles .................................... 407
Introduction .................................................. 407
Five-Membered Nitroazoles ..................................... 408
Nitrobenzazoles ............................................... 423
Conclusions ................................................... 423
References .................................................... 424
Abbreviations ................................................. 433
Index ......................................................... 435


Архив выставки новых поступлений | Отечественные поступления | Иностранные поступления | Сиглы
 

[О библиотеке | Академгородок | Новости | Выставки | Ресурсы | Библиография | Партнеры | ИнфоЛоция | Поиск | English]
  Пожелания и письма: branch@gpntbsib.ru
© 1997-2020 Отделение ГПНТБ СО РАН (Новосибирск)
Статистика доступов: архив | текущая статистика
 

Документ изменен: Wed Feb 27 14:24:22 2019. Размер: 10,921 bytes.
Посещение N 1014 c 04.12.2012